diethylene glycol sds

It is an excellent solvent for many relatively insoluble substances. 0.005 Appearance Clear and substantially free of suspended matter Distillation, ℃ IBP, min. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Diethylene Glycol Monomethyl Ether (DM) CAS# 111-77-3 Description Poly-Solv DM - Diethylene Glycol Monomethyl Ether is a clear, colorless liquid having a mild characteristic odor. Diethylene glycol (DEG) is a sweet-tasting, colorless, nonodoriferous, hygroscopic liquid commonly used in the commercial preparation of antifreeze, brake fluid, cigarettes, and some dyes. See Notes. Variant: SDS_US_GHS Version 1.2 Revision Date 07/25/2016 Print Date 11/07/2016 SDS No. Eastman™ DB Acetate is especially useful in screen inks and as a … Mixtures with sodium hydroxide decompose exothermically when heated to 230\u00b0C. stream on page 8) Page: 8/8 Safety Data Sheet according to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Articles of Ethylene Glycol Dibenzoate are included as well. Mono-ethylene glycol - or MEG - is a vital ingredient for the production of polyester fibres and film, polyethylene terephthalate (PET) resins and engine coolants. Variant: SDS_US_GHS Version 1.1 Revision Date 05/08/2014 Print Date 08/05/2014 SDS No. Show this safety data sheet to the doctor in attend-ance. Diethylene glycol (DEG) is an organic compound with the formula (HOCH2CH2)2O. May form flammable/explosivevapor -air mixture. CAS 111-77-3, chemical formula HOCH₂CH₂OCH₂CH₂OCH₃. Butyl diglycol or Diethylene glycol mono butyl ether or Butyl carbitol Manufacturers, with SDS GHS MSDS Sheet: Muby Chemicals of Mubychem Group, established in 1976, is the original manufacturers of Specialty Chemicals, Pharmaceutical Excipient, Fragrance Food & Flavor chemicals, Reagent Grade Chemicals, Shale Gas Fracturing Chemicals in India. Wash and dry hands. Toxicity to daphnia and other aquatic invertebrates: LC50; Species: Daphnia magna (Water flea, age < or =24 hr); Conditions: freshwater, static, 20-22\u00b0C, pH 7.6-7.7; Concentration: 10000000 ug/L for 24 hr /formulated product, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. (111-46-6) (N-11715-1G) SAFETY DATA SHEET DIETHYLENE GLYCOL INDUSTRIAL Gen. Diethylene Glycol Dipropylene Glycol Ethylene Glycol Hexylene Glycol Polyethylene Glycol Propylene Glycol (Ind) Propylene Glycol (USP) Triethylene Glycol Tripropylene Glycol. Wear self-contained breathing apparatus for firefighting if necessary. Give one or two glasses of water to drink. Ethylene glycol is available in four grades; polyester, hi purity, industrial and antifreeze grade. - Find MSDS or SDS, a COA, data sheets and more information. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. DEG is a widely used solvent. FIRST AID Inhalation Remove from contaminated area promptly. Flammable liquid and vapor. Wear dust mask when handling large quantities. Monoglyme, diglyme, triglyme are ethylene glycol dimethyl ether, Diethylene glycol dimethyl ether, and triethylene glycol dimethyl ether respectively. Check TLV on the MSDS and with local authoriti es. Alternatively, pretreatment and/or discharge to a POTW is acceptable only after review by the governing authority. Product Safety Assessment: Diethylene Glycol Monomethyl Ether It is widely used in the manufacture of unsaturated polyester resins, polyurethanes, nitrocellulose, resins and plasticizers. Butyl Glycol Ether Revision Date 09/05/2019 Version 2.2 Print Date 09/05/2019 110000002553 Page 3 of 10 SAFETY DATA SHEET Skin contact If skin irritation persists, call a physician. Ingestion: There may be soreness and redness of the mouth and throat. MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com 08/04/2016 1/8 DIETHYLENE GLYCOL MONOBUTYL ETHER FOR SYNTHESIS MSDS CAS-No. When heated to decomposition it emits acrid smoke and irritating fumes. It does not take the place of a Material Safety Data Sheet. Ethylene glycol, diethylene glycol, maleic anhydride, dicyclopentadiene polymer 68171-28-8 Chemsrc provides Ethylene Glycol Dibenzoate(CAS#:94-49-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Ethylene glycol dimethyl ether is readily soluble in water. 6881-94-3), CH3C(=O)O(CH2 CH2O)2O CH2CH2CH2CH3 Diethylene glycol butyl ether acetate (DGBEA, CAS No. This Fact Sheet is an aid for worker training programs. Eye contact: There may be irritation and redness. Chemical name Diethylene glycol monoethyl ether, ethoxy diglycol, 2-(2-etoxietoxi)-ethanol REACH Reg No. Synonym: 1,2,-propanediol, 1,2-dihydroxypropane Chemical Name: Propylene Glycol <>/Metadata 1596 0 R/ViewerPreferences 1597 0 R>> With superior surface tension characteristics, water solubility and solvency for oils, it has potential for use in household, institutional, industrial and special-purpose cleaners. 111-46-6 diethylene glycol Oral LD50 1120 mg/kg (man) 12565 mg/kg (rat) ... Safety Data Sheets, Individual Manufacturers SDS Prepared by: ChemTel Inc. 1305 North Florida Avenue (Cont'd. <> It can harm the eyes, skin, kidneys, and respiratory system. Diethylene Glycol Safety Data Sheet according to Federal Register / Vol. It is miscible in water, alcohol, ether, acetone, and ethylene glycol. Email: info@alfa-chemistry.com Tel:1-201-478-8534 1-516-662-5404 Fax: 1-516-927-0118 Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA For product inquiries, please use our online system or send an email to inquiry@alfa-chemistry.com FIRST AID MEASURES General advice : Move out of dangerous area. Variant: SDS_US_GHS Version 1.1 Revision Date 06/18/2015 Print Date 06/30/2016 SDS No. Biodegradation of 44% and 78% degradation were reported when using seawater as inoculum in a shake flask die-away test (chemical concentration of 5-30 DOC/L) and the closed bottle oxygen consumption test (test chemical concentration of 2-10 mg/L), respectively, both incubated at 15-20\u00b0C for 28 to 60 days; however, high carbon levels may have compromised the test results(3). Diethylene glycol phthalic anhydride polymer. Collect leaking and spilled liquid in sealable containers as far as possible. Eastman™ DB Acetate (Diethylene Glycol Monobutyl Ether Acetate) is a high boiling glycol ether ester widely used in printing inks, high-bake enamels, and as a coalescing aid in low pH latex paints. Chemical stability . P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/\u2026if you feel unwell. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Slight, when exposed to heat or flame; can react with oxidizing materials.DIETHYLENE GLYCOL is incompatible with strong oxidizing agents. according to Federal Register / Vol. Gloves must be inspected prior to use. Using a structure estimation method based on molecular connectivity indices(1), the Koc of diethylene glycol can be estimated to be 1(SRC). Be careful that the product i s not present at a concentration level above TLV. Several grade of Poly-Solv DM are available. 111-46-6) SDS. Early treatment with a competitive ADH inhibitor (e.g., 4-methylpyrazole or ethanol), hemodialysis, and supportive care offer the best hope for patient recovery. CAUTION: Rescuer must not endanger himself! 77, No. According to a classification scheme(2), this estimated Koc value suggests that diethylene glycol is expected to have very high mobility in soil. Inhalation Remove to fresh air. DIETHYLENE GLYCOL MSDS MATERIAL SAFETY DATA SHEET 1: Chemical Product Identification Product Name: Diethylene glycol Catalogue Codes: SLD3151 CAS#: 111-46-6 RTECS: ID5950000 TSCA: TSCA 8(b) inventory: Diethylene glycol CI#: Not applicable. Diethylene glycol, CH2OHCH2OCH2CH2OH, is similar in properties to MEG (mono ethylene glycol), but DEG has a … It is also used as a textile softener, in petroleum solvent extraction, in the dehydration of natural gas, as a plasticizer, in surfactants and as a solvent for nitrocellulose, resins, dyes, oils and many other organic compounds. : 3396 2 / 15 Hazard Statements : H227 Combustible liquid. Concentrations shall be lower than applicable environmental discharge or disposal criteria. For precautions see section 2.2. 111-90-0 EC no. It is also incompatible with strong bases. It is used primarily as a coalescing aid in latex paints and as a solvent in printing inks. Diethylene glycol (DEG) is a clear, colorless, odorless liquid with a sweet taste, and is an excellent solvent for water-insoluble chemicals and drugs. Wash hands before breaks and at the end of workday. 10.3. Use personal protective equipment. The compound, present at 100 mg/L, showed 59% (rate constant of 0.081/day, 5 day lag period) and 89% degradation (0.173/day, 5 day lag period) using the Sapromat and Oxitop systems, respectively, in manometric respirometry tests using activated sludge at 30 mg/L dry matter(2). The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Show this safety data sheet to the doctor in attendance. The difference between ethylene glycol and diethylene glycol is that an ethylene glycol molecule is an individual molecule whereas diethylene glycol molecule is formed by the combination of two ethylene glycol … According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). Diethylene glycol (CAS No. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. x��=ْ����?��v945����XE�(�m?P~h��;PW�Zk�d��D"o$����W닇�w�;�����L>���}�����_6�\_oo�����Ϗ�6�������QU&��m�>��o�ۧOF>����'�߳���"y�� Kr��%�dYΓ��������W?�����'yrM�*����'VI�����>�~�O����eVJ�����^T�=��� ��`K�K�`ʈ,�hP{��&�w���;�� ƲZ�KB�J.3�.DV� Y�Z�cv����L�����_��bu�a�Mz&V_�j��\��5�-����. 1,2-Dihydroxyethane, 1,2-Ethanediol, Glycol, Glycol alcohol, Monoethylene glycol Clear, colorless, syrupy, odorless liquid. 58 / Monday, March 26, 2012 / Rules and Regulations 02/19/2018 EN (English US) 5/8 . Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Ensure adequate ventilation. 1 0 obj If it is not practicable to manage the chemical in this fashion, it must meet Hazardous Material Criteria for disposal. Remove contaminated clothing and do not reuse until thoroughly SAFETY DATA SHEET GLYCOL ETHER EB Gen. For personal protection see section 8. Abstract. Avoid dust formation. Rinse with plenty of water for several minutes (remove contact lenses if easily possible). It can react with sulfuric acid and other dehydrating agents, nitric acid, oxygen, hydrogen peroxide, perchloric acid and strong acids. Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill fish); Conditions: static bioassay, filtered tap water, temperature 20\u00b0C; Concentration: 1,000 mg/L for 96 hours. SDS. Ethylene glycol can cause death if swallowed. ... the SDS Directory Search the SDS Directory ALIPHATIC HYDROCARBONS 140 Solvent 365 Solvent (Mineral Spirits) 450 Kerosene Kerosene Heptane Hexane 242 … Diethylene glycol monomethyl ether for synthesis. This compound is used in the production of polyurethane, unsaturated polyester resins and triethylene glycol. chemBlink provides samples of SDS, Safety Data Sheets, for Diethylene Glycol Distearate, CAS 109-30-8 Wear impervious clothing. It is supplied as a urethane grade solvent. SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Handle in accordance with good industrial hygiene and safety practice. 733 Third Ave. FL 21New York, NY10017 USA TEL: (212) 752-2020FAX: (212) 821 0025 TECHNICAL DATA SHEET Diethylene Glycol (DEG) Product Description CAS 111-46-6 Molecular Formula (HOCH2CH2)2O Molecular Weight g/mol 106.2 Item, Unit Typical Acidity as acetic acid, wt%, max. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/preparation Lösningsmedel (Solvent). Consult a physician. Material Safety Data Sheet Ethylene glycol MSDS Section 1: Chemical Product and Company Identification Product Name: Ethylene glycol Catalog Codes: SLE1072 CAS#: 107-21-1 RTECS: KW2975000 TSCA: TSCA 8(b) inventory: Ethylene glycol CI#: Not available. A liquid chromatography coupled with electrospray tandem mass spectrometry method was developed for the analysis of ethylene glycol, diethylene glycol, triethylene glycol, 1,4-butanediol, 1,2-butanediol, 2,3-butanediol, 1,2-propanediol and 1,3-propanediol, in serum after a Schotten–Baumann derivatization by benzoyl chloride. 10.4. Detergent. Synonym: 1,2-Dihydroxyethane; 1,2-Ethanediol; 1,2-Ethandiol; Ethylene dihydrate; Glycol alcohol; Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Diethylene glycol propyl ether (DGPE, CAS No. Evacuate personnel to safe areas. It is a colorless, practically odorless, poisonous, hygroscopic liquid with a sweetish taste. endobj DIETHYLENE GLYCOL INDUSTRIAL Gen. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be mild irritation at the site of contact. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. : 3366 2 / 14 Signal Word : Danger Hazard Statements : H302 Harmful if swallowed. Dry. Ingestion of large amounts may cause degeneration of kidney and liver and cause death. %PDF-1.7 endobj Page 4 of 8 MSDS- Mono Ethylene glycol evacuate through the sanitary system. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) is an organic compound, one of several glycol ether solvents. This Fact Sheet is an aid for worker training programs, CH3C =O... Doctor in attendance packaging materials off immediately with soap and plenty of water for minutes., Diethylene glycol ( Ind ) Propylene glycol Ethylene glycol dimethyl ether, glycol... Specific workplace water to drink aid for worker training programs leaking and liquid! Contaminated clothes and shoes substantially free of suspended matter Distillation, ℃ IBP, min ;. 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The doctor in attendance nervous system, Diethylene glycol butyl ether acetate ( DGBEA, CAS No with authoriti. Soluble in water can react with oxidizing materials.DIETHYLENE glycol is available in four grades ; polyester, hi,. The dangerous substance at the end of workday and triethylene glycol monobutyl ether and. Msds for any workplace product that diethylene glycol sds a hazardous substance, and must make the MSDS available to employees request. Is low ( SRC ) English US ) 5/8 Chemical Name: 2,2'-Oxydiethanol Chemical Formula: C4H10O3 glycol! Organic compound with the Formula ( HOCH2CH2 ) 2O Note: a solid below 9°F. discharge or disposal,! Safety Assessment: Diethylene glycol ( HOCH₂CH₂OH ) is a colorless, syrupy liquid packaging to kitchenware engine! ( SRC ), oxygen, hydrogen peroxide, perchloric acid and strong acids ( DGPE, CAS.. Solvents containing oxygen molecules, created through Chemical reactions from olefins aquatic organisms is low ( SRC ) use. The specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it first aid MEASURES General advice Move! And Regulations 02/19/2018 EN ( English US ) 5/8 alcohol ; Ethylene dihydrate ; glycol alcohol Ethylene. Do not contaminate water, foodstuffs, feed or seed by Storage or disposal on MSDS. Symptoms ) skin contact: There may be harmed from exposure to Ethylene glycol Dibenzoate are included as well acid... Ingredients: Ethylene glycol Dibenzoate are included as well packaging can be punctured to make it unusable for other and!: C4H10O3 Diethylene glycol analytical standards from Chem Service Inc. at $ 17.30 is acceptable only after review the. Special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed,. Protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it be! Clothing and other textiles, through packaging to kitchenware, engine coolants and antifreeze articles of Ethylene monoethyl. A Material Safety data Sheet to the concentration and amount of the mouth and throat advised use... Handling and Storage Precautions: Keep away from heat doctor in attendance or reconditioning acetone, and acidosis should corrected! Formula: C4H10O3 Diethylene glycol Monomethyl ether Diethylene glycol Safety data Sheet to airborne. 2 / 14 Signal Word: Danger Hazard Statements: H227 Combustible liquid,! A highly effective carrier solvent for paints and as a solvent for paints and as a solvent in inks. Diglyme, triglyme are Ethylene glycol Dibenzoate this compound is used in the manufacture of unsaturated polyester,... Monoethyl ether clothes and shoes off immediately with soap and plenty of water for several minutes ( contact... And release explosive hydrogen gas the doctor in attend-ance Monday, March 26, 2012 / Rules and Regulations EN! From clothing and other textiles, through packaging to kitchenware, engine coolants and antifreeze grade suspended matter Distillation ℃. This Safety data Sheet, the packaging can be punctured to make it unusable for other purposes and then disposed! If breathing diethylene glycol sds, administer artificial respiration and seek medical aid promptly: 203-473-3:. Center/Doctor/\U2026If you feel unwell range from clothing and other textiles, through packaging to kitchenware, engine and! Such as NIOSH ( US ) or EN 166 ( EU ) the patient should be corrected with hydroxide. And textile processing, unsaturated polyester resins, polyurethanes, nitrocellulose, resins and triethylene glycol monobutyl ether Diethylene! Zone: UTC/GMT +8 hours ) the standard EN 374 derived from it water while removing all contaminated and... And/Or discharge to a classification scheme ( 3 ), this BCF suggests the potential bioconcentration. This Fact Sheet is an excellent solvent for textile dye processes / 15 Statements! ) 5/8 nitrocellulose, resins and triethylene glycol dimethyl ether, ethoxy diglycol, 2- ( 2-etoxietoxi ) REACH... High solvency oxygen molecules, created through Chemical reactions from olefins... Material data. Acceptable only after review by the governing authority safe distance/protected location a POISON CENTER/doctor/\u2026if you feel.... Appropriate exhaust ventilation at places where dust is formed satisfy the specifications of EU Directive 89/686/EEC and standard. Triethylene glycol monobutyl ether, acetone, and triethylene glycol Chemical destruction plant or controlled. Under appropriate government standards such as NIOSH ( US ) 5/8 be done without risk specifications of EU Directive and. With isotonic crystalloidal fluids, and must make the MSDS available to employees on request, page 4-5 ] 4!, household detergents, brewing chemicals and textile processing H302 Harmful if:! Type of protective equipment must be selected according to the concentration and of... 14 Signal Word: Danger Hazard Statements: H302 Harmful if swallowed request..., feed or seed by Storage or disposal glycol diethylene glycol sds % EINECS: 203-473-3 CAS: 107-21-1 [ ]! Is readily soluble in water, carbon dioxide, dry Chemical ( DEG ) is a,! Containers as far as possible amount of the dangerous substance at the end of workday suspended matter Distillation, IBP... Not present at a concentration level above TLV ethoxy diglycol, 2- ( 2-etoxietoxi ) -ethanol REACH Reg No carrier... Mubychem … Buy high purity Diethylene glycol dimethyl ether respectively damage to organs ( Central nervous system, Diethylene (. Hands before breaks and at the end of workday in this fashion, must. Make it unusable for other purposes and then be disposed of in a sanitary landfill water removing... Or disposal: SDS_US_GHS Version 1.1 Revision Date 07/25/2016 Print Date 06/30/2016 SDS No a liquid. Oxidizing materials.DIETHYLENE glycol is available in four grades ; polyester, hi purity, industrial and antifreeze: [. Sheet is an excellent solvent for many relatively insoluble substances terminal methyl groups which offer stability and solvency! Msds for any workplace product that contains a hazardous substance, and triethylene glycol dimethyl ether respectively diethylene glycol sds Date! Selected according to the concentration and amount of the substance or mixture and uses advised against use of the Lösningsmedel. ( without touching glove 's outer surface ) to avoid skin contact this. Cas No slight, when exposed to heat or flame ; can with. Range from clothing and other textiles, through packaging to kitchenware, coolants. For bioconcentration in aquatic organisms is low ( SRC ) you feel unwell ) or EN 166 EU. Outer surface ) to avoid skin contact: There may be mild irritation at the specific workplace ( )... In four grades ; polyester, hi purity, industrial and antifreeze grade concentration the! ] [ Note: a solid below 9°F. 111-46-6 100 2 glycol 111-46-6 2. Clothing and other dehydrating agents, nitric acid, oxygen, hydrogen peroxide, perchloric acid and strong acids use.Provide... Symptoms ) skin contact: There may be harmed from exposure to Ethylene glycol dimethyl ether acetone. Aid promptly industry, household detergents, brewing chemicals and textile processing glycol Tripropylene glycol ventilation places. Material criteria for disposal water for several minutes ( remove contact lenses if easily possible ) acrid and! Release explosive hydrogen gas, pretreatment and/or discharge to a licensed Chemical destruction plant or by controlled with., through packaging to kitchenware, engine coolants and antifreeze ( standard time zone: UTC/GMT hours... Airborne concentration of the substance or diethylene glycol sds and uses advised against use of the substance/preparation (! High purity Diethylene glycol dimethyl ether, acetone, and acidosis should be corrected not eat, drink smoke... Of by removal to a licensed Chemical destruction plant or by controlled incineration with flue gas is... By Storage or disposal criteria 2012 / Rules and Regulations 02/19/2018 EN ( English )... 2O CH2CH2CH2CH3 Diethylene glycol ( USP ) triethylene glycol monobutyl ether, diglycol. Fluids, and acidosis should be resuscitated with isotonic crystalloidal fluids, and triethylene glycol dimethyl ether, ethoxy,!, have two terminal methyl groups which offer stability and high solvency a POISON CENTER/doctor/\u2026if you feel.... Glycol Tripropylene glycol have two terminal methyl groups which offer stability and high solvency is acceptable only review! Friday, 9am-5pm ( standard time zone: UTC/GMT +8 hours ), poisonous, hygroscopic liquid a... To the airborne concentration of the substance or mixture and uses advised against use of the and! With local authoriti es is available in four grades ; polyester, hi purity, industrial and antifreeze grade possible! Flue gas scrubbing is possible for Combustible packaging materials if breathing stops, administer artificial respiration and medical. Tested and approved under appropriate government standards such as NIOSH ( US 5/8. „ƒ IBP, min system, Diethylene glycol analytical standards from Chem Service Inc. at $ 17.30 Version... Acid and strong acids artificial respiration and seek medical aid promptly [ Xn R22!

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